|
Penguin Composite Population Graph

|
"In fact the change in the air and in
sunlight in the next few decades may pose more danger to animals and plants
than to human beings. Laboratory tests show that UV-B can damage fish, shrimp,
and crab larvae, copepods, krill, and the zooplankton and phytoplankton
at the base of the food chains in the sea. A 10% increase in UV killed almost
all (phytoplankton) specimens. Since the Ozone Hole is going to be with us for
at least one hundred years, we could cause an evolutionary upheaval if
thousands of species in the sea weaken and others more resistant to these rays
take over. The billions of krill in Antarctic waters - which are shrimp-like
crustaceans - depend on the phytoplankton. Baleen whales, sperm whales, squid,
seals, the albatross and the penguin are among the many creatures that depend
on the krill. El-Sayed (researcher) suspects that krill may be among the first
casualties of the Ozone Hole. 'If anything happens to the krill,' he has said,
'the whole ecosystem will collapse. We can say good-bye to the whales, to the
seals, to the penguins, et cetera.'"
Jonathan Weiner, The Next One Hundred
Years, 1990. |

Since Mr. Weiner's book was published in 1990,
it has been widely reported that 90% of the krill in Antarctic waters have
disappeared. In 2001 penguins from the Antarctic began arriving on the beaches
in Rio de Janeiro. It was not a regular migration. It has never happened
before. Penguins were forced to make the swim of several thousand miles because
there is a severe lack of food source in their native habitat. This development
is particularly ominous for baleen and sperm whales which are more directly
dependent upon the krill. The general media has yet to report a clear linkage
of these events. They are probably trying to find some way to put some kind of
spin on it which will allow for the preservation of the illusion that the earth
has not been overpopulated by humans. This is an example of predictions by
scientists which have come true much sooner than publicly stated because their
original predictions had been intentionally conservative so as not to be seen
as alarmist. The north polar ice cap was found to have melted through in 2000,
fifty years ahead of schedule. In all likelihood the large Antarctic ice shelf
will break off far ahead of schedule as well. It is interesting to note that
NASA has announced in late August 2001 that an important satellite monitoring
ozone will be discontinued since the piddling cost of ten million dollars has
been labelled excessive. Just when the information the satellite could provide
is needed more than ever before. It makes you wonder just what the heck their
priorities really are. By far one of the most powerfull tools for obtaining the
necessary scientific information and at a critical time of need. They just say,
"Oh, well. We don't need it anymore." Which is more important the information,
or the lack of it.


The opportunity for conservation of penguin
numbers in order to preserve the illusion that humans have not overpopulated
the planet may have passed. The halogen containing compounds which participate
in the radical chain reaction mechanisms which break down ozone started to be
phased out just at the end of the 20th century. Production of certain
halocarbons was stopped in industrialized nations. The production was continued
in other countries. Humans finally woke up and drastically reduced certain
halocarbons used as refrigerants and aerosol sprays. That was a nice first
step. Although it was a baby step, it was in the right direction. But then
other halocarbons were substituted for the ones whose production had been
reduced. Many more halocarbon compounds are in production. It may be true that
humans can find substitutes for halocarbons. Thus far however, humans have
substituted some halocarbons with other halocarbons. And the stratospheric
ozone hole has become a large and permanent feature of polar meteorology.
The stratosphere. The stratosphere is where
ozone functions to reduce UV radiation. Halocarbon compounds which have been
released into the atmosphere thus far have not yet reached the stratosphere.
The peak concentration levels have yet to be reached in the stratosphere both
globally and at the poles. Halocarbon effects do have a decay curve. That curve
is measured in many decades. If halocarbon production were completely halted
tomorrow, humans could count themselves lucky if concentration levels peaked in
a decade or two. The probability that that will happen is low. Halocarbon
production will not stop tomorrow. They are indispensible for too many
processes which make a high technology life style possible. Human numbers are
increasing exponentially. Furthermore, every effort is being made to globalize
the convenient high technology lifestyle which will increase halocarbon release
into the atmosphere. What does this mean? It does not mean that convenience is
bad. Nor that high technology is bad. Nor that poor people shouldn't have cars,
houses, TVs, refrigerators and toilets. Although that is how these sorts of
statements in combination with the HOP word are routinely misinterpreted. What
this does mean is simply that peak stratospheric halogen concentrations are not
within sight. it means that the situation is bad. The situation will get worse.
And it will be a long time before it gets better.


Ozone is needed in the stratosphere, especially
at the poles. Even after peak halogen concentration levels have been achieved,
ozone will not be restored suddenly. Not even. The radical chain mechanisms by
which halogens break down ozone are catalytic in nature. An atomic chlorine
radical, for example, breaks down thousands of ozone molecules. It doesn't stop
until it bumps into nitrogen. Only a millionth part of the stratosphere is
ozone. It's amazing that molecules measured in parts per million, billion, or
trillion, should matter to such a big planet. If all the ozone in the
atmosphere were spread out on the ground it would form a layer about as thin as
a piece of canvas. That's not very much. The thinner the ozone layer in the
stratosphere becomes, the higher the ratio of catalyst to substrate. Under
conditions of excess catalyst, the equilibrium for halogen initiated radical
chain reactions with ozone will lie far to the product side. As more and more
halogen compounds reach the stratosphere, conditions of excess catalyst merely
become conditions of super excees catalyst.
Ozone is an unnatural or at least, unusual
molecule. It is thermodynamically unstable. Ozone does not want to be ozone.
molecular orbitals. Electron sharing by the three oxygens. negatively charged
atomic chlorine or other halogen radical presents its electron to ozone, one
oxygen accepts the electron very very readily. When ozone levels becme one
tenth the starting level and the catalytic molecules' concentration is
increased a thousand fold, the possibility of oxygen reforming the
thermodynamically precarious triad, ozone, will become more and more
remote.
There is a feedback loop for increasing the
ozone destruction and keeping it that way at the Arctic. Ozone, even at the
minute parts per trillion levels found in the atmosphere above the Antarctic,
had previously been adequate for warming, p 160
The ozone hole in the stratosphere above the
Antarctic is a large and permanent reality now. It is not some hypothetical
product of a gloomy doomy mind. It is real. It is tangible. It is measurable.
And it has reduced the krill by 90%. that is very bad news. It is just one more
prediction which has come true far sooner than conservatively estimated. Helped
by the condition of apalling and unnecessary scientific illiteracy.
|